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、、[1][2]、、、、[3]。、、、、Fe3+、Al3+、Ca2+Cl-、SO42-、SiO32-。、、。1、[4]。TEOS、。[5]TEOSHSPACTEOS-PAC。TEOS、。TEOS-PACHS-PACTEOS-PAC、、、、。[6]2.0mol·L-1Si/AlNaAlO2B[7]。PASCAl、PASCSiAl。Al13/AlbPASCAl13-[8]。、111231.1633182.1634143.163414),,。,。TQ314.235A1000-3770(2009)08-019-042008-12-09105310351965－0459-6503786E-mailchenying648617@163.com0459-6503431E-maildouya0403@163.com35820098TECHNOLOGYOFWATERTREATMENTVol.35No.8Aug.,200919DOI:10.16796/j.cnki.1000-3770.2009.08.005。、、、。[9]FC,FC,,FC,。FC。、、。、、、、[10]。[11]PSAF,。,PFS,,COD25%28%SS10%。PSAF,,,,、,,,,。2AlFeSiB、Mn、CaZn[12]。[13][14-16]。[17]、PFSSBPFSSBCOD、pHCOD、、PFS。。PF-SSB。、、、、(SCPAFC)。SCPAFCCOD90%95.5%SS95%Cr3+85%PAC[18]。B、Zn。[19]B、ZnPSFZB。、、。PSFZB[20]100d。。、[21]、[22][23]。3。[24]。[25]。。。[26]、35820Nano-PFSS、、pH、。Nano-PFSS。96.6%93.2%COD53.8%。Nano-PFSS。。[27-29][30]-TiO2PACTiO2-PAC。TiO2-PACCODPACAlCl3。。TiO2PAC、。。。4[31]、pH、、、[32]。Takaara[33]。[34]、、2、、pH。2.5～3.0pH7.0～8.590%PSAMF。pH7.0～10.0PSAMF99%。[35]Fenton-PSAFB。Fenton-PSAFB95.2%COD84.2%BOD581.5%、。COD、SS、。5。1、2。、、3。[1]RadoiuMT,MartinDICalinescuI,etal.Preparationofpoly-electrolytesforwastewatertreatment[J].JournalofHazardousMa-terials,2004,106B:27-37.[2]SpinelliLS.Influenceofpolymerbasesonthesynergisticeffectsobtainedfrommixturesofadditivesinthepetroleumindustry:Performanceandresidueformation[J].PetrolSciEng.,2006,11(9):1-8.21RESEARCHPROGRESSOFINORGANICPOLYMERCOMPOSITEFLOCCULANTSANDTHEIRAPPLICATIONINWATERTREATMETNTChenYing1,ZhangYawen1,SunXue1,HuDongsheng2,PengBingqian3(1.SchoolofChemistryandChemicalEngineeringDaqingPetroleumInstituteDaqing163318China2.7OilProductionCompanyDaqingOilfieldCompanyLimitedDaqing163414,China3.9OilProductionCompanyDaqingOilfieldCompanyLimitedDaqing163414China)AbstractInordertomatchtherequirementsofwatertreatmentengineering,considerableattentionwaspaidtodevelopcompositeinorganicpolymerfloccu-lantsduringrecentyears.Theameliorationofflocculantpreparationprocessandtheachievementsoftheirapplicationsonwatertreatmentandthepossiblemechanismsofflocculationactionwerediscussedrespectively.SomesuggestiononresearchanddevelopmentofflocculantsinChinawereputforward.Keywordscompositeinorganicpolymerflocculants;wastewatertreatment;improvement[3],.[J].,2004,30(6):315-319.[4]BYGao,HHHahn,EHoffmann.Evaluationofaluminum-sili-catepolymercompositeasacoagulantforwatertreatment[J].Wa-terResearch,2002,(36):3573-3581.[5],,,.[J].,2004,24(1):15-18.[6],,,.[J].:,2005,40(5):97-102.[7]PerryCC,ShafranKL.Thesystematicstudyofaluminumspecia-tioninmediumconcentratedaqueoussolution[J].JInorganicBio-chemistry,2001,87:115-124.[8]VKazpard,BSLartiges,CFrochot,etal.FateofcoagulantspeciesandconformationaleffectsduringtheaggregationofamodelofahumicsubstancewithAl13polycations[J].WaterRe-search,2006(40):1965-1974[9],.[J],2007,27(9):45-47.[10].[J].,2000,29(2):102-104.[11],,,.[J].,2004,5(12)52-54,92.[12],,.[J].,2007,7(16):42-45.[13],,,.[J].,2005,25(4):317-319.[14]BesraL,SenguptaDK,etal.Influenceofpolymeradsorptionandconformationonflocclationanddewateringofkaolinsuspension[J].SepPurifTechnol.,2004,37(3):231-246.[15]PierceRH,HenryMSHighamCJ,etal.Removalofharmfulal-galcellsandtoxinsfromseawaterculurebyclayflocculation[J].HarmfulAlgae,2004,3(2):141-148.[16],,.[J].,2006,22(7):38-41.[17],,,.[J].,2006,26(1)70-73[18],,.[J].,1994,2(4):41-43.[19],,,.[J].,2005,18(6):13-15[20]YubinZeng,JunboumPark.Characterizationandcoagulationperformanceofanovelinorganicpolymercoagulant-poly-zinc-silicate-sulfate[J].ColloidsandSurfacesA:PhysicochemicalandEngineeringAspects,200821:59-64.[21],,.[J].,2006,26(5):425-428.[22],,.[J].,2006,25(9):1078-1082.[23],,.[J].,2003,3(2):44-46.[24],,.[J].,1996,29(5):111-114.[25],.[J].,2008,37(5):533-537.[26],,.[J].:,2008,38(2):153-156.[27],,.[J].,2006,(1):17-22.[28],,,.-[J].,2000,17(3):155-159.[29]JamesRO.Characterizationofcolloidsinaqueoussystems[J].AdvancesinCeramics,1987,21(1):349-410.[30],,,.TiO2-PAC[J].,2000,17(3):155-159.[31]YanMingquan,WangDongsheng,YouShijie,etal.Enhancedco-agulationinatypicalNorth-Chinawatertreatmentplant[J].WaterResearch,2006(40):3621-3627.[32]LiuHailong,WangDongsheng,WangMin,etal.Effectofpre-o-zonationoncoagulationwithIPF-PACls:Roleofcoagulantspeci-ation[J].ColloidsandSurfacesA:PhysicochemEngAspects2007,(294):111-116.[33]TomokoTakaara,DaisukeSano,HiroshiKonno,etal.Cellularpro-teinsofMicrocystisaeruginosainhibitingcoagulationwithpolya-luminumchloride[J].WaterResearch,2007,(41):1653-1658.[34],,,.[J].,2008,2(3):328-333.[35],,,.Fenton-[J].,20071(1):37-40.35822